#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 16/03/2020

data_5yOhtAoR
_audit_creation_date            2020-03-16
_audit_creation_method          "Bilbao Crystallographic Server"

_citation_journal_abbrev        "Dalton Trans."
_citation_journal_volume        46
_citation_page_first            6921
_citation_page_last             6933
_citation_article_id            ?
_citation_year                  2017
_citation_DOI                   10.1039/c7dt00975e

loop_
_citation_author_name
"D. Xu"
"M. Sale"
"M. Avdeev"
"C.D. Ling"
"P.D. Battle"




_atomic_positions_source_database_code_ICSD  257626
_atomic_positions_source_other               .

_transition_temperature  3.5
_experiment_temperature  1.6

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM5+ 2  2  special  primary  3  .

_exptl_crystal_magnetic_properties_details
;
NPD
Positional structure from a determination at 3K
;

_active_magnetic_irreps_details
;
1k magnetic structure
k-maximal magnetic symmetry (6 possible)
2-dim irrep along a special direction as primary
FM along b
;

_parent_space_group.name_H-M_alt  'P 4/n b m'
_parent_space_group.IT_number                       125
_parent_space_group.transform_Pp_abc  'a,b,c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 0]

_parent_space_group.child_transform_Pp_abc  'a,b,c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,b,c;1/2,0,0'



_space_group_magn.number_BNS  50.282
_space_group_magn.name_BNS  "P b' a n'"
_cell_length_a             9.54770
_cell_length_b             9.54770
_cell_length_c             4.77910
_cell_angle_alpha          90.00
_cell_angle_beta           90.00
_cell_angle_gamma          90.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1
2 -x+1/2,y,-z,+1
3 -x,-y,-z,+1
4 x+1/2,-y,z,+1
5 x,-y+1/2,-z,-1
6 -x+1/2,-y+1/2,z,-1
7 -x,y+1/2,z,-1
8 x+1/2,y+1/2,-z,-1

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Zr1 Zr 0.25000 0.25000 0.50000
Co1 Co 0.00000 0.00000 0.50000
Ge1_1 Ge 0.51720 0.25000 0.00000
Ge1_2 Ge  0.25000 0.51720 0.00000
O1 O 0.62760 0.37240 0.17550
O2_1 O 0.16330 0.07300 0.26360
O2_2 O  0.42700 0.16330 0.26360

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
Co1 2.10(5) 1.45(8) 0.00000 mx,my,mz

