#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 19/03/2020

data_5yOhtAoR
_audit_creation_date            2020-03-19
_audit_creation_method          "Bilbao Crystallographic Server"

_citation_journal_abbrev        "PHYSICAL REVIEW B"
_citation_journal_volume        96
_citation_page_first            ?
_citation_page_last             ?
_citation_article_id            024409
_citation_year                  2017
_citation_DOI                   10.1103/PhysRevB.96.024409

loop_
_citation_author_name
"J. Blasco"
"J.L. Garcia-Munoz"
"J. Garcia"
"G. Subias"
"J. Stankiewicz"
"J.A. Rodriguez-Velamazan"
"C. Ritter"




_atomic_positions_source_database_code_ICSD  .
_atomic_positions_source_other               .

_transition_temperature  60
_experiment_temperature  2

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM2+  1  1  .  primary  9  .

_exptl_crystal_magnetic_properties_details
;
NPD
Non-standard parent setting P2_1/n
The magnetic ordering of Tm takes place below 30K without symmetry break
The orientation of Tm moments in the figure of the reference is inconsistent with moment values given in the text. The text values have been assumed correct.
;

_active_magnetic_irreps_details
;
1k magnetic structure
k-maximal magnetic symmetry (4 possible)
1-dim irrep as primary
;

_parent_space_group.name_H-M_alt  'P 2_1/c'
_parent_space_group.IT_number                       14
_parent_space_group.transform_Pp_abc  'a,b,a+c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 0]

_parent_space_group.child_transform_Pp_abc  'a,b,c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,b,a+c;0,0,0'



_space_group_magn.number_BNS  14.79
_space_group_magn.name_BNS  "P 2_1'/c'"
_cell_length_a             5.18943
_cell_length_b             5.54304
_cell_length_c             7.41935
_cell_angle_alpha          90.00
_cell_angle_beta           89.674
_cell_angle_gamma          90.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1
2 -x,-y,-z,+1
3 -x+1/2,y+1/2,-z+1/2,-1
4 x+1/2,-y+1/2,z+1/2,-1

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Tm1 Tm 0.0208 0.0732 0.2520
Co1 Co 0.50000 0.00000 0.50000
Mn1 Mn 0.50000 0.00000 0.00000
O1 O 0.3005 0.3173 0.0541
O2 O 0.3222 0.2934 0.4423
O3 O 0.6123 0.9626 0.2561

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
Tm1 -1.38(7) 0.92(4) 1.42(5) mx,my,mz
Co1 1.13(9) 0.00000 -2.60(5) mx,my,mz
Mn1 1.13    0.00000 -2.60 mx,my,mz

