#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 10/23/2022

data_5yOhtAoR
_audit_creation_date            2022-10-23
_audit_creation_method          "Bilbao Crystallographic Server"

_chemical_name_systematic
;
;
_chemical_name_common                    ?
_chemical_formula_moiety                 ?
_chemical_formula_structural             ?
_chemical_formula_analytical             ?
_chemical_formula_iupac                  ?
_chemical_formula_sum                    "Tb5 Ni2 In4"
_chemical_formula_weight                 ?
_chemical_melting_point                  ?
_chemical_compound_source                ?
_chemical_absolute_configuration         ?


_citation_journal_abbrev        "J. Phys.: Condens. Matter"
_citation_journal_volume        2
_citation_page_first            .
_citation_page_last             .
_citation_article_id            476001
_citation_year                  2015
_citation_DOI                   10.1088/0953-8984/27/47/476001

loop_
_citation_author_name
"C. Ritter"
"A. Provino"
"P. Manfrinetti"
"V. K. Pecharsky"
"K. A. Gschneidner"
"S. K. Dhar"

_temperature_position_structure         130
_temperature_atom_positions             0
_temperature_non-magn_atom_positions    0
_temperature_cell_parameters            0

_atomic_positions_source_database_code_ICSD  .
_atomic_positions_source_other               .

_transition_temperature     125
_experiment_temperature     50

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mGM2+ 1 1 . primary 3 .

_exptl_crystal_magnetic_properties_details
;
NPD
Positional structure from a determination at 130K
FM along c
Other magnetic phases are reported below 30K
;

_active_magnetic_irreps_details
;
1k magnetic structure
k-maximal magnetic symmetry
1-dim irrep
;

_parent_space_group.name_H-M_alt  'P b a m'
_parent_space_group.IT_number                       55
_parent_space_group.transform_Pp_abc  'a,b,c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 0]

_parent_space_group.child_transform_Pp_abc  'a,b,c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,b,c;0,0,0'

_space_group_magn.number_BNS  55.357
_space_group_magn.name_BNS  "P b' a' m"
_space_group_magn.point_group_name  "m'm'm"
_space_group_magn.point_group_number  "8.4.27"
_cell_length_a                 17.89320
_cell_length_b                 7.90740
_cell_length_c                 3.59430
_cell_angle_alpha              90.00
_cell_angle_beta               90.00
_cell_angle_gamma              90.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1 
2 -x,-y,z,+1 
3 -x,-y,-z,+1 
4 x,y,-z,+1 
5 x+1/2,-y+1/2,-z,-1 
6 -x+1/2,y+1/2,-z,-1 
7 -x+1/2,y+1/2,z,-1 
8 x+1/2,-y+1/2,z,-1 

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1 

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Tb1 Tb 0.00000 0.00000 0.00000 1
Tb2 Tb 0.22200 0.24560 0.00000 1
Tb3 Tb 0.41570 0.11870 0.00000 1
Ni1 Ni 0.30500 0.02580 0.50000 1
In1 In 0.57110 0.20700 0.50000 1
In2 In 0.84710 0.07050 0.50000 1

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
_atom_site_moment.magnitude
_atom_site_moment.spherical_azimuthal
_atom_site_moment.spherical_polar
Tb1 0.0 0.0 -8.0(1) 0,0,mz 8.0(1) ? ?
Tb2 0.0 0.0 0.0 0,0,mz 0.0 ? ?
Tb3 0.0 0.0 -6.4(1) 0,0,mz 6.4(1) ? ?

