#\#CIF_2.0
# Created by the Bilbao Crystallographic Server
# http://www.cryst.ehu.es
# Date: 09/09/2018 17:36:10

data_5yOhtAoR
_audit_creation_date            2018-09-09
_audit_creation_method          "Bilbao Crystallographic Server"

_citation_journal_abbrev        "Inorg. Chem."
_citation_journal_volume        56
_citation_page_first            2750
_citation_page_last             2762
_citation_article_id            ?
_citation_year                  2017
_citation_DOI                   10.1021/acs.inorgchem.6b02905

loop_
_citation_author_name
"D. Xu"
"M. Avdeev"
"P.D. Battle"
"X.-Q. Liu"




_atomic_positions_source_database_code_ICSD  .
_atomic_positions_source_other               .

_transition_temperature  4.5
_experiment_temperature  1.6

loop_
_irrep_id
_irrep_dimension
_irrep_small_dimension
_irrep_direction_type
_irrep_action
_irrep_modes_number
_irrep_presence
mZ5-  2  2  special  primary  3  .

_exptl_crystal_magnetic_properties_details
;
NPD
;

_active_magnetic_irreps_details
;
k-maximal magnetic symmetry (6 possible)
2-dim irrep active restricted to a special direction of maximal symmetry
;

_parent_space_group.name_H-M_alt  'P  4/n  b  m'
_parent_space_group.IT_number                       125
_parent_space_group.transform_Pp_abc  'a,b,c;0,0,0'

loop_
_parent_propagation_vector.id
_parent_propagation_vector.kxkykz
k1 [0 0 1/2]

_parent_space_group.child_transform_Pp_abc  'a,b,2c;0,0,0'
_space_group_magn.transform_BNS_Pp_abc  'a,-c,b;0,0,1/4'



_space_group_magn.number_BNS  52.315
_space_group_magn.name_BNS  "P_b  n  n  a"
_cell_length_a             9.73690
_cell_length_b             9.73690
_cell_length_c             9.62520
_cell_angle_alpha          90.00
_cell_angle_beta           90.00
_cell_angle_gamma          90.00

loop_
_space_group_symop_magn_operation.id
_space_group_symop_magn_operation.xyz
1 x,y,z,+1
2 x,-y+1/2,-z,+1
3 -x+1/2,-y+1/2,z+1/2,+1
4 -x+1/2,y,-z+1/2,+1
5 -x,-y,-z+1/2,+1
6 -x,y+1/2,z+1/2,+1
7 x+1/2,y+1/2,-z,+1
8 x+1/2,-y,z,+1

loop_
_space_group_symop_magn_centering.id
_space_group_symop_magn_centering.xyz
1 x,y,z,+1
2 x,y,z+1/2,-1

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Ce1 Ce 0.25000 0.25000 0.25000
Co1 Co 0.00000 0.00000 0.25000
Ge1_1 Ge 0.52440 0.25000 0.00000
Ge1_2 Ge  0.25000 0.52440 0.00000
O1 O 0.63100 0.36900 0.09030
O2_1 O 0.16190 0.06420 0.12845
O2_2 O  0.43580 0.16190 0.12845

loop_
_atom_site_moment.label
_atom_site_moment.crystalaxis_x
_atom_site_moment.crystalaxis_y
_atom_site_moment.crystalaxis_z
_atom_site_moment.symmform
Co1 2.29(2) 1.19(3) 0.00000 mx,my,mz

